![]() ![]() Next door in the Netherlands, the violence was even worse. ![]() Police have made some arrests, but it is not immediately clear how many. Some protesters were seen throwing projectiles at riot police and in response, officers fired water cannon and tear gas at the group. Nearly 40,000 people descended on the capital Brussels to protest against new anti-Covid measures banning the unvaccinated from entering restaurants and bars. For years, I have been warning that this sort of civil unrest would be coming in the future. And I think that does not bode well for the troubled times ahead. Way too often, the bad guys are starting to get the upper hand in situations like this. The door of the garage slowly closes as the protesters continue to confront the police, with one demonstrator even trying to push open the garage door. The group of nearly a dozen officers are seen backing up into a garage. The footage shows a crowd of angry protesters aggressively yelling at the police dressed in full riot gear. Video captured the moment protesters in Portland cornered police in a garage during riots over the Kyle Rittenhouse verdict. At one point, about a dozen police officers were forced back into a garage by an extremely unruly mob… Over in Portland, approximately 150 rioters started fires and smashed things up following the Kyle Rittenhouse verdict. For even more examples, please see my recent article entitled “In Some Parts Of America, Looting Has Become A Way Of Life”. Louis Vuitton San Francisco, Union square got cleared out!! /7Sz6rlRo8nĮven though this sort of thing is taking place so frequently now, I am still shocked whenever I see these sorts of videos. Many of the looters got away, but police were able to nail a few of them. The Louis Vuitton in San Francisco union square just got emptied out □ /Imi6qbL0i1 Meanwhile, the Louis Vuitton store in San Francisco was also hit by organized looters this weekend. “There was a mob of people,” he continued. “I probably saw 50-80 people in like ski masks with crowbars, a bunch of weapons,” he said. Chang’s restaurant across from the Nordstrom store. This happened in one of the most prosperous areas of northern California, and one eyewitness described it as “like a scene out of a movie”…īrett Barrette is one of the managers of P.F. At least two people arrested at gunpoint. #Breaking About 25 cars just blocked the street and rushed into the Walnut Creek Nordstrom making off with goods before getting in cars snd speeding away. This sort of “organized crime” is becoming increasingly common, but the size and scale of this particular attack was particularly alarming. All three individuals were treated for their injuries on scene. Needless to say, Nordstrom workers were caught entirely off guard, and several individuals received injuries during the melee…ĭuring the theft, two Nordstrom workers were punched and kicked, while another was sprayed with pepper spray. The robbery was over within minutes as thieves armed with crowbars and wearing ski masks streamed out of the Nordstrom into the dozens of cars lining the block. More than 80 people stormed and robbed a Nordstrom in California on Saturday night, according to a police report from the Walnut Creek Police Department. A mob of more than 80 thieves wearing ski masks and armed with crowbars suddenly descended upon a Nordstrom store, and they ransacked the entire place in just minutes… ![]() If you think that I am being overly dramatic, just consider what happened in northern California on Saturday night. We are literally watching our entire society slowly but surely go down the tubes, and it is heartbreaking to watch. But the truth is that what we are experiencing is not even close to “normal”. To a certain extent, a lot of these things seem “normal” to many of us at this point. We have become accustomed to soaring murder rates, mass shootings, extreme degeneracy throughout the entire entertainment industry, violent rioting in our streets and severe corruption on all levels of government. Our civilization is crumbling right in front of our eyes.
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![]() ![]() The other annoying thing about this app is the fact that the video is about 3-5 seconds behind the audio.Īll in all, two stars may well be too generous. Please select another video.” Then I had to quit the app and reload it, scroll through all the networks, again, before I could get back to the game. The buffering is not too annoying now, since I now have 200mbps internet speed, but I just got a message that “…the video you are watching is no longer available. It seems that each year I find some changes to the app, but the games become more and more difficult to find, as I have to scroll through every available network until I get to the. Admittedly, my internet speed was only 100mbps. The next year, they made some changes which made the games a bit more difficult to find and the buffering continued. The first year I got the subscription as a gift and it was fairly easy to find the game I wanted to watch, but the app buffering was really annoying. This is the third year I’ve subscribed to this app, and each year it just gets worse. We do not endorse the streaming of copyright-protected material without the permission of the copyright holder.IPTV Smarters Player has no affiliation with any third-party provider whatsoever.IPTV Smarters Player does not supply or include any media or content.To unlock the new features, you have to buy the premium version. Premium Version: As we have removed the Ads but added some new features. Ěbility to open “ List of episodes” on the Video Player (NEW).Ěbility to open the channel list on the Video Player(NEW). ![]()
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Ross wala na bang pag ibig minus one 20 week ultrasound.Ī pamucna posteljina bethesda md weather cam flymo 500 xt spare, back parts.Ī pakistan islamic relief angelito tierno para bautizo cena fastum gela best country football songs mine. ![]() ![]() ![]() More information on the The Showdown is available at the Official Website. One of her most impressive victories was from the black side of a Hedgehog in rapid.ġ. Since blitz and rapid chess are particularly strong points for Hou, she continued to increase her lead with each phase of the match. In Fischer Random, however, Hou evened the score and then soon took over the lead.Īccording to GM Alejandro Ramirez, "Despite never having played Fischer Random in a tournament setting, she showed absolutely dominance over the nuances of development, pawn structure and piece placement in every single game." Here is his game from the White side, defeating a Sicilian Dragon.ġ. One of the highlights of the match was Negi's brilliantly played double victory in basque chess. Here is the final scoreboard for the match: ![]() Rxg2 e1=Q) and Black's king makes it f2 to support the pawns' promotion long before White's king can help.īy game 16, Caruana had secured the match victory with two games to spare. Kxa8 Ke5 White's rook is paralyzed by Black's advanced passed pawns (70. Can you find Caruana's winning move, played with only seconds left on the clock?Ħ6.Be4! and Nakamura immediately resigned. The surprise was that Caruana took over in the first blitz game and didn't let up.Ĭaruana admitted, "I was ready to take a draw in the first game" until he saw the key move at the last moment. This isn't a surprise: Nakamura is ranked #1 in the world in FIDE blitz ratings. Nd6 1-0 BlitzĮven though Nakamura was a point behind in match points, commentators GM Yasser Seirawan and WGM Jennifer Shahade still considered him the favorite. The highlight was Caruana's precise positional play to turn a slight advantage into a victory.ġ. He managed 3 points out of the 4 games, going undefeated. RapidĪlthough Nakamura is the higher rated rapid player, Caruana took over the lead in this phase of the match. WGM Jennifer Shahade described this position as "pretty wild" because "both bishops aim at the enemy king".īy the end of the day, Nakamura, the more experienced Fischer Random player, emerged with a one point lead in the match. Here were the starting positions that gained the most votes: White then adopts a formation with pawns on c4 and e4 and Black curls up in a Hedgehog. These structures arise when the black c-pawn is exchanged early on for the white d-pawn (as in the Sicilian Defence). Twitter followers of given eight possibilities chosen by Kasparov himself, ranging from "traditional" to "very chaotic", to vote on. An understanding of Hedgehog structures is an essential component in any chessplayer’s knowledge. It is also often referred to as Chess960 because there are 960 possible starting positions. Qe6+ Kh7 1/2-1/2įor the Fischer Random rounds, the organizers allowed viewers at home to participate by choosing the starting positions.įischer Random: The starting positions of the pieces on the back rank are randomized. With the white pieces, Caruana also seemed to have an advantage until Nakamura uncorked 21.e4!?, a positional pawn sacrifice to activate his pieces. An understanding of Hedgehog structures is an essential component in any chessplayer’s knowledge. Caruana missed this continuation and instead played 13.Ne7, allowing Nakamura to equalize. ![]() ![]() ![]() While plain backdrops are a good choice for people who want to direct all attention to the person of interest in the video, fancy backdrops make a video seem more professional and can still be neutral and not draw too much attention off of the YouTuber if done properly. If you can’t find a brick wall nearby to film as your backdrop, there are plenty of cheap photography backdrop clothes that feature different shades of brick wall textures. Brick Wall Backdropīrick walls are a popular choice for YouTube backdrops because they are visually interesting and give a bit of color while still being neutral. Wall tapestries have the added bonus of being able to be left up as a decorative element even when not filming. Wall tapestries are particularly good for this purpose and come in many different colors and designs to suit anyone’s particular style of video. ![]() Quilts and tapestries make good impromptu YouTube backdrops, as they incorporate eye-catching color and design without drowning out the foreground of the video. This fabric is available in many different colors and can be accentuated through other background objects to create a minimalist yet stylish look. Muslin is a non-reflective cotton that makes an appropriate background for photography and video filming. This can make your entire backdrop look more dynamic without changing anything else about the background. To achieve a backlit haloed lighting effect, install a small scoop light behind the person in the video. When using a plain backdrop, you have a little bit more flexibility with influencing lighting and the way it affects the person in the video. Rolls of kraft paper can be found in most art supply stores.Ĭhoosing a paper backdrop in a gray or dark blue background is most flattering to most people, but you can also choose different colors according to the mood you’re trying to achieve. You can always use a paper backdrop for your video if you want a backdrop that is both economical and can be easily traded out and replaced as you want to change things up. ![]() ![]() Just be sure you have the curtains secured tightly before filming, as it will ruin your take if the curtain falls down halfway through. Curtains are usually made of aesthetically pleasing fabrics but tend to also be neutral. If you film your video near a window with curtains, you can always stretch those curtains sideways across the wall and tack them up to form a quick backdrop for YouTube videos. If you’re wanting to avoid a lot of distraction in the background of your YouTube video so that the viewer focuses only on the person speaking in the video, you’ll want to go with a plain or solid-colored backdrop. Read on to learn more about different kinds of DIY YouTube backdrops you can use to make your videos more professional and fun to watch. There are many different ways you can tweak your YouTube video backdrop for increased likes and subscribers. In this post, I put together 50 ideas you can use for your DIY YouTube video backdrop spread across these categories: Bad backdrops are just as much of a negative impact on the quality of a video as a poor audio track is. These boring, distracting, or plain bad backdrops can be detrimental to a video’s main message and can cause people to unsubscribe or not subscribe at all. I thought I would do you a solid and pull together all the things I learned you could make into great backdrops. When I created my own DIY Studio, I spent a considerable amount of time looking through Pinterest and blog posts looking for ideas, but couldn’t find a solid source with all the ideas in one place. While it seems like everybody and their brother has a YouTube vlog these days, all that self-promoted video media has come with some pretty shoddy backdrops. ![]() ![]() ![]() Hydride Ion Affinities as a Measure of Stability 87Ģ.6.3 Molecul ar Mech anics on Biomolecules andĢ.6.4 Molecu lar Mech anics Studies of Reactions 136Ģ.3 Rela tionships Between Struc ture and Energe ticsBasic Conformationa l Analysis 92Ģ.3.1 Acyclic Systems-Torsiona l Poten tial Surfaces 92 Group Orbitals of Representative TI Systems:ġ.4 Bonding and Structures of Reactive Intermediates 52Ģ.1 Thermochemistry of Stable Molecules 66Ģ.1.4 An Introduction to Potential FunctionsĢ.1.5 Heats of Formation and Combustion 77Ģ.2 Thermoch emistry of Reactive Interm ediates 82 The Effects of Heteroatoms-Formaldehyde 40 Using Grou p Orbitals to Make Ethy lene 38 Putting the Electrons In- The MH 2 System 33ġ.3 Orbital Mixing-Building Larger Moleculesġ.3.1 Using Group Orbitals to Make Ethane 36 Putting the Electrons In - The MH3 System 33 Model of Bonding in Organic Structures 26ġ.2 A More Modern Theory of Organic Bonding 26 The Organic Structures of Biology 1057ġ.1.1 Quantum Numbers and Atomic Orbitals 4ġ.1.2 Electron Configurations and Electronic Diagramsġ.1.7 A Hybrid Valence Bond / MolecularOrbitalġ.1.13 Summary of Concepts Used for the Simplest Representative Examples Using Simple Molecules 1051Ĥ. Group Orbitals of Common Functional Groups: ![]() Electrostatic Potential Surfaces for Representative Organic Moleculesģ. Conversion Factors and Other Useful DataĢ. Organic Polymer and Materials Chemistry 753Įlectronic Structure: Theory and ApplicationsĪdvanced Concepts in Electronic Structure Theoryġ. Organotransition Metal Reaction Mechanisms and Catalysisġ3. Substitutions at Aliphatic Centers and Thermalġ2. Reactions Involving Additions and / or Eliminations 537 Molecular Recognition and Supramolecular Chemistry 207Įxperiments Related to Thermodynamics and Kinetics 421 Solutions and Non-Covalent Binding Forces 145 Introduction to Structure and Models of Bonding 3 In cludes bibliographi cal references and index.ġ. Library o f Congress Cataloging-in-Publica tion DataĪn slyn, Eric V., 1960Modern physical organic chemistry I Eric V. Shou ld be addressed to the Permissions Department, University Science Books. Requests for permission or furth er informatio n Section 107 or 108 of the 1976 Un ited Sta tes Copyright Act w ithout the permission Reprodu ction or transla tion of any part o f this work beyond tha t permitted by This book is p rinted on acid-free paper.Ĭop yright © 2006 by University Science Books Printe r & Binder: Edwards Brothers, Inc. Electronic Structure: Theory and ApplicationsContents Introduction to structure and models of bonding Strain and stability Solutions and non-covalent binding forces Molecular recognition and supramolecular chemistry Acid-base chemistry Stereochemistry Energy surfaces and kinetic analyses Experiments related to thermodynamics and kinetics Catalysis Organic reaction mechanisms, Part 1: reactions involving additions and/or eliminations Organic reaction mechanisms, Part 2: substitutions at aliphatic centers and thermal isomerizations/rearrangements Organotransition metal reaction mechanisms and catalysis Organic polymer and materials chemistry Advanced concepts in electronic structure theory Thermal pericyclic reactions Photochemistry Electronic organic materials Conversion factors and other useful data Electrostatic potential surfaces for representative organic molecules Group orbitals of common functional groups : representative examples using simple molecules The organic structures of biology Pushing electrons Reaction mechanism nomenclatureĬompositor: Wilsted & Taylor Publishing Services Reactivity, Kinetics, and Mechanisms III. Molecular Structure and Thermodynamics II. ![]() ![]() ![]() ![]() WWE 2017 can be installed and played on Android Smartphones and Tabs using the instruction guide below So from here, you can easily download wwe2k APK + OBB file for Android from website. WWE 2k game download for android – apk+data obb full mobile game – Download WWE 2k Apk and its Data File for Android Free, there is a link provided below you can Download the WWE 2k Apk, and Data for Android Free with one single click.In this playground, gamers will be playing the role of muscular wrestlers, choose costumes and participate in fierce battles on the ring. This is a sports game that specializes in free wrestling on Android. Download WWE 2K Apk (Original) for Android.Use a variety of kicks, throws and other moves. Train your character and improve his abilities. You can choose from a variety of different fighters, each with unique characteristics and appearance. 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This is one of the ones I haven’t played however, I hear excellent things about it, so it’s on my list to play in the near future. ![]() English language downloads of each game are available for free via vgperson, but consider supporting the developer by shelling out $3 for them on Steam. Unlike Ib, the Strange Men games do generally involve running and fighting from time to time, so be warned if “panic-horror” isn’t really your jam. Hoffman’s sinister take on him, as opposed to the kindly one that many stories paint him as) The Boogie Man takes on that most nebulous of monsters used so often to frighten children into obedience and The Hanged Man looks back to the tarot. The Strange Men SeriesĬonsisting of four games, Uri’s Strange Men series draws its inspiration from nursery rhymes and fairy tales: The Crooked Man riffs off the rhyme that begins, “There was a crooked man” The Sand Man deals with the mythological figure known mostly for putting people to sleep (although this version is more along the lines of E.T.A. A free English language download is available from vgperson.ĭownload it for free here. The focus is on the story and on puzzle-solving it’s not a battle-heavy game. In many ways, it’s somewhat Alice In Wonderland-esque - but it’s also a thing all its own. Developed by kouri, the game centers around a small girl - Ib, pronounced “Eeb” - who, while visiting a museum with her well-to-do parents, gets transported into a topsy-turvy world where nothing is more dangerous than a painting. I’m starting with my favorite: Ib is magical and frightening and delightful and sad, sometimes all at once. Some bullet points have multiple games include within them, by the way, so all in all, there are a total of 21 options here. Those are the games you’ll find here - games that have been passed around by word of mouth for years, many of which are only now receiving wider releases thanks to platforms like Steam and Playism.Ī few notes: I’ve played many of these games, and if I haven’t, I’ve either watched other people play them, or I’ve heard them recommended enough times and in glowing enough terms that I think they’re worth including. I’m also fudging the name “RPG Maker” a bit although many of the games I’ve included here were actually made with some version of RPG Maker or another, some of them were made with an engine called WOLF RPG Editor, a free alternative to RPG Maker.Įither way, though, they’re all worth checking out - and as a bonus, many of them are cheap or free. Now, more than 25 years on, there’s a wealth of creepy games made with various versions of RPG Maker floating around out there - many of which have had lasting influence on the world of horror gaming in particular, as well as the world of gameplay development more generally. A burgeoning community of developers making games intended to unsettle, frighten, and terrify players emerged shortly thereafter, each using the engine in unique ways that pushed and pulled at their players - at the things that scare us the most. The very first version of RPG Maker as we know it today was released in 1992 - and although it was geared towards making turn-based RPG games rendered in pixelated graphics, developers quickly realized its potential for other genres and styles when used in a way that thought outside the proverbial box. ![]() The paired-down graphics of the engine make good writing an absolute necessity for a successful game, so when developers get RPG Maker horror games right, they really get them right. But when it comes to horror games, I will always, always think that less is more - which is why I am so frequently taken by creepy games made with RPG Maker. Previously: The Best Horror Video Games, March 2016.ĭon’t get me wrong: I enjoy a big budget video game title with crisp, realistically rendered graphics as much as the next gal. ![]() ![]() ![]() Related Post: 5 Best Survival Backpacks To Carry All Your GearĪny prepper or backpacker knows that having the right tools to start a fire is an absolute necessity when you’re out in the wild. Once you’ve got your bug out bag, it’s time start building your bag with survival gear. The best news is that, at the time of writing, this bug out bag sells for a fraction of the price of similar bags. There’s even a padded compartment that can fit a laptop or other sensitive gear. ![]() By the way, these compartments are waterproofed to keep your gear dry. There are a total of 10 compartments that can help keep you and your survival gear organized. The padded shoulder straps make carrying this bug out bag very comfortable and there is a chest strap that can sinch this bag down tight to keep it in place if/when you need to run. The Combat Bag’s zipper and clips are heavy duty and long lasting. It’s constructed of 600D Polyester which makes it tough as nails. It’s the bug out bag that I personally use by the way. The EVATAC™ Combat Bag is a badass bug out bag and an ideal pack for anyone serious about putting together a legit bug out bag. You only have to make sure your bug out bag list includes items to address the following needs:Īnd now let's begin with a rookie mistake. Knowing which essentials to prioritize in your bug out bag list to survive an unexpected disaster situation is a must.īuilding your own customized bug out bag is not so hard or complicated. What Should You Have In Your Bug Out Bag? Bug Out Bag Essentials
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